SYNTHESIS OF A COMPOSITE MEMBRANE FILTER FOR THE FILTRATION PROCESS OF METHYLDIETHANOLAMINE (MDEA) SOLUTION USED IN THE PURIFICATION OF NATURAL GASES FROM H2S AND CO2 GASES
Main Article Content
Abstract
Amine solutions are widely used to remove sour components (primarily H2S and CO2) from natural gas and light hydrocarbon gases. Removal of solids from amine solutions is essential for the efficient operation of gas purification plants. In this work, flat-surface composite membranes were synthesized using a phase inversion method based on polyvinylidene fluoride (PVDF) mixed with polyethylene glycol (PEG) and polyacrylonitrile (PAN). The use of polyvinylidene fluoride (PVDF), polyacrylonitrile (PAN), and polyethylene glycol (PEG) in a ratio of 15:5:5 in the preparation of the composite membrane allowed an amine solution flux increase of 18% during the filtration process and a ~97% removal of mechanical particles from the amine solution. These results were proven to be associated with an increase in the porosity and hydrophilicity of the surface of the PVDF composite membranes.
Downloads
Article Details
Issue
Section

This work is licensed under a Creative Commons Attribution 4.0 International License.
Public License Terms
(For Open Journal Systems (OJS))
-
Copyright:
The copyright of the published article remains with the author(s). However, after publication, the article is distributed on the OJS platform under the Creative Commons (CC BY) license. -
License Type:
This article is distributed under the Creative Commons Attribution 4.0 International (CC BY 4.0) license. This means users can utilize the article under the following conditions:- Copy and distribute: The text of the article or its parts can be freely distributed.
- Quote and analyze: Parts of the article can be used for quoting and analysis.
- Free use: The article can be freely used for research and educational purposes.
- Attribution: Users must provide proper attribution and reference to the original source.
-
Commercial use:
The article can be used for commercial purposes, provided that authorship and source are properly cited. -
Document modification:
The text or content of the article can be modified or adapted, as long as it does not harm the authorship. -
Liability disclaimer:
The author(s) are responsible for the accuracy of the information contained in the article. The editorial team of the platform is not liable for any damages resulting from the use of this information. -
Public usage obligations:
The content of the article must be used only in accordance with legal and ethical standards. Unauthorized use is strictly prohibited.
Note:
These license terms are designed to ensure transparency and openness in material usage. By accepting these terms, you agree to the adaptation and distribution of the article content under the terms of the Creative Commons license.
Link: Creative Commons Attribution 4.0 International (CC BY 4.0)
How to Cite
References
1. Alcheikhhamdon Y, Hoorfar M (2016) Natural gas quality enhancement: A review of the conventional treatment processes, and the industrial challenges facing emerging technologies. Journal of Natural Gas Science and Engineering 34:689-701. doi: https://doi.org/10.1016/j.jngse.2016.07.034 DOI: https://doi.org/10.1016/j.jngse.2016.07.034
2. Stewart MI (2014) Chapter Nine - Gas Sweetening. In: Stewart MI (ed) Surface Production Operations (Third Edition), vol 2. Gulf Professional Publishing, Boston, pp 433-539. doi: https://doi.org/10.1016/B978-0-12-382207-9.00009-3 DOI: https://doi.org/10.1016/B978-0-12-382207-9.00009-3
3. Bazhenov SD, Novitskii EG, Vasilevskii VP, Grushevenko EA, Bienko AA, Volkov AV (2019) Heat-Stable Salts and Methods for Their Removal from Alkanolamine Carbon Dioxide Absorbents (Review). Russian Journal of Applied Chemistry 92 (8):1045-1063. doi: https://doi.10.1134/S1070427219080019 DOI: https://doi.org/10.1134/S1070427219080019
4. Scanlan TJ (2014) Filter media selection in amine gas sweetening systems. 3M Purification Inc. doi: https://multimedia.3m.com/mws/media/984043O/tab-filter-media-selection-in-amine-gas-sweetening-systems.pdf
5. Dumée L, Scholes C, Stevens G, Kentish S (2012) Purification of aqueous amine solvents used in post combustion CO2 capture: A review. International Journal of Greenhouse Gas Control 10:443-455. doi: https://doi.org/10.1016/j.ijggc.2012.07.005 DOI: https://doi.org/10.1016/j.ijggc.2012.07.005
6. Vitse F, Baburao B, Dugas R, Czarnecki L, Schubert C (2011) Technology and pilot plant results of the advanced amine process. Energy Procedia 4:5527-5533. DOI: https://doi.org/10.1016/j.egypro.2011.02.539
7. Бобрешова, О. В. О числах переноса в электромембранных системах / О. В. Бобрешова, E. Н. Коржов, Т. Ш. Харебава и др. // Электрохимия. – 1983. – Т. 19. – С. 1668-1671.
8. Брикенштейн, М. А. Применение электродиализа с ионитовыми мембранами для выделения пиридина и триэтилами на из их солей / М. А. Брикенштейн, К. И. Крыщенко, В. Н. Царев, О. Н. Ефимов // Хим. пром-сть. – 1975. – № 3. – С. 178-181.
9. Вейцер, Ю. И. Высокомолекулярные флокулянты в процессах очистки природных и сточных вод / Ю. И. Вейцер, Д. М. Минц, – М.: Стройиздат, 1984. – 200 с.
10. Гауптман, З. Органическая химия / З. Гауптман, Ю. Грефе, Х. Ремане – М.: Химия, 1979. – 832 с.
11. Гнусин, Н. П. Исследование электрохимических свойств промышленых биполярных мембран / Н. П. Гнусин, В. И. Заболоцкий, Н. В. Шельдешов [и др.] // Журнал прикладной химии. – 1980. – Т. 53. – С. 1069-1072.
12. Махсумов, А. Г., & Хайитов, Ж. К. (2022). СИНТЕЗЫ, БИОЛОГИЧЕСКАЯ АКТИВНОСТЬ БИС-АРОМАТИЧЕСКИХ ПРОИЗВОДНЫХ МОЧЕВИНЫ. Universum: технические науки, (1-3 (94)), 5-14.
13. Хайитов, Ж. К., Махсумов, А. Г., Валеева, Н. Г., & Шапатов, Ф. У. (2020, May). N, N1–гексаметилен бис-[(1-аминодифенил)-мочевины] и его механизм образования. In Международная онлайн конференция «Инновации в нефтегазовое промышленности, современная энергетика и их актуальные проблемы», г. Ташкент (Vol. 26, pp. 378-379).
14. Bakhtishod, A., & Temurbek, S. (2024). EFFECT OF INITIAL SOLVENT SLURRY INSIDE THE REACTOR FOR FISCHER-TROPSCH SYNTHESIS. Sanoatda raqamli texnologiyalar/Цифровые технологии в промышленности, 2(1), 171-180.
15. Абдуллаев, Б. М., Сайфуллаев, Т. Х., & Мирзаев, С. Ф. (2023). КАТАЛИТИЧЕСКИЙ ПРЯМОЙ СЕРОВОДОРОД ПРОЦЕСС ОКИСЛЕНИЯ. JOURNAL OF MULTIDISCIPLINARY BULLETIN, 6(5), 319-326.
16. Abdullaev, B. M., & Sayfullaev, T. K. (2024). COBALT FISCHER–TROPSCH CATALYST REGENERATION. JOURNAL OF MULTIDISCIPLINARY BULLETIN, 7(1), 105-113.